Chapter 5 · Evaluation and Analysis

Fitting the measured values (see Fig. 5.6) yields the following parameter values A and B when C is set to zero:

Original thesis figure or equation on PDF page 82
Original thesis figure or equation on PDF page 82

Figure 5.6. Viscosity according to Eq. (5.7), solid line, with the fitted background contribution ηbg, dotted line.

A shear-rate correction is not required, since it becomes significant only extremely close to the critical point [53]. The measurement range relevant to light scattering lies close to the critical point. In this region the following relation holds, involving the system-dependent amplitude Q₀ [23]:

Original thesis figure or equation on PDF page 82

Here the critical viscosity exponent is Zη = 0.065, and ξ is the correlation length, which is discussed in a later chapter.